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生态学杂志 ›› 2025, Vol. 44 ›› Issue (5): 1699-1710.doi: 10.13292/j.1000-4890.202505.042

• 综合评述 • 上一篇    下一篇

二硫化钼纳米材料的环境行为及其生态毒性研究进展

张瑜,赵晨旭,金彩霞,张杏丽,张国庆,邹威*   

  1. (河南师范大学环境学院, 黄淮水环境与污染防治教育部重点实验室, 河南新乡 453007)
  • 出版日期:2025-06-10 发布日期:2025-05-15

Research progress of environmental behaviors and ecotoxicity of molybdenum disulfide nanomaterials.

ZHANG Yu, ZHAO Chenxu, JIN Caixia, ZHANG Xingli, ZHANG Guoqing, ZOU Wei*   

  1. (School of Environment, Key Laboratory of Yellow River and Huai River Water Environment and Pollution Control, Ministry of Education, Henan Normal University, Xinxiang 453007, Henan, China).

  • Online:2025-06-10 Published:2025-05-15

摘要: 作为当前最受关注的二维过渡金属硫化物纳米材料之一,二硫化钼(MoS2)因其优异的物理、化学和生物学性质被广泛应用在多个领域。在其生产、使用和处理处置过程中,MoS2纳米颗粒不可避免地通过多种途径释放进入环境,对生态系统的影响和潜在威胁不容忽视。本文系统总结了MoS2纳米颗粒释放进入水体后的迁移转化行为研究进展,重点分析了典型环境因子的影响及作用机理;综述了纳米MoS2对水生动植物、陆生动植物和微生物的毒性效应及相关机制,阐明了MoS2生态毒性与其理化特征(粒径、形貌、晶相结构和元素掺杂等)之间的内在关联;最后,对今后纳米MoS2环境行为和生态毒性领域的研究方向进行了展望,以期为同类型人工纳米材料在生态环境领域的研究及应用提供借鉴和参考。


关键词: 人工纳米颗粒, 生态毒理, 迁移转化, 影响因素, 构效关系

Abstract: As one of the most concerned transitional metal dichalcogenides nanomaterials, molybdenum disulfide (MoS2) has been widely applied in various fields due to its unique physical, chemical and biological properties. During the production, use, and disposal, MoS2 nanomaterials inevitably enter the environment through multiple pathways. The potential threat of MoS2 nanomaterials to ecosystems cannot be ignored. We summarized the research progress regarding the migration and transformation behaviors of MoS2 after releasing into aquatic environments, and discussed the effects and mechanisms of environmental factors. We reviewed the toxicity effects and associated mechanisms of MoS2 nanomaterials on plants, animals, and microorganisms, and elucidated the relationships between the ecotoxicity and physicochemical characteristics of MoS2 (e.g., size, morphology, crystal structure, and element doping). We proposed the outlook regarding the research of environmental behaviors and ecotoxicity of MoS2 nanomaterials, aiming to provide guidance for the research and application of nanomaterials in the same type in ecology and environment field.

Key words: engineered nanoparticle, ecotoxicology, migration and transformation, influencing factor, structure-activity relationship