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酸性煤矿排水中硫的迁移转化及其与铁的相互作用——以贵州织金废弃煤矿区为例

王悦竹1,张瑞雪1,2*,吴攀1,2,3,夏雨1,宋传孝1,吴一凡1   

  1. (1贵州大学资源与环境工程学院, 贵阳 550025;2贵州省普通高等学校矿山环境污染过程与控制特色重点实验室, 贵阳 550025;3贵州大学国土资源部喀斯特环境与地质灾害重点实验室, 贵阳 550025)
  • 出版日期:2018-12-10 发布日期:2018-12-10

Sulfate migration and transformation in relation to iron in acid mine drainage: A case study from the waste coal mine area, Zhijin County, Guizhou Province.

WANG Yue-zhu1, ZHANG Rui-xue1,2*, WU Pan1,2,3, XIA Yu1, SONG Chuan-xiao1, WU Yi-fan1   

  1. (1College ofResources and Environmental Engineering, Guizhou University, Guiyang 550025, China; 2Key Laboratory of Process and Control of Mining Environmental Pollution, Colleges and Universities in Guizhou Province, Guiyang 550025, China; 3Key Laboratory of Karst Environment and Geohazard, Ministry of Land and Resources, Guizhou University, Guiyang 550025, China).
  • Online:2018-12-10 Published:2018-12-10

摘要: 硫酸盐是酸性煤矿排水的主要组成部分,高浓度硫酸盐废水排到环境中会产生一系列污染及环境效应。本文选取贵州省织金县珠藏镇酸性煤矿排水相对集中的小流域为对象,采集了水体与沉积物样品,研究硫酸盐在喀斯特地区酸性煤矿排水中的迁移转化过程。结果表明:研究区水体酸化明显,水中溶解态硫主要以SO42-形式存在,且SO42-随水的迁移过程有明显的衰减,亚稳态硫含量较少;可交换态硫酸盐(ExS)是沉积物中硫的主要存在形态,约占总硫(TS)的65%,还原态硫在这种强氧化环境中含量很少,各还原态硫含量的大小顺序是元素硫(ES)<酸可挥发性硫化物(AVS)<铬还原态硫化物(CRS);水体中SO42-和Fe(Ⅲ)存在明显的正相关关系,SO42-与Fe(Ⅲ)相结合共沉淀到沉积物中是SO42-衰减的重要原因。

关键词: 生态敏感性评价, CA-Markov, 南昌市, 城市开发边界

Abstract: Sulfate is the main component of acid mine drainage. High concentrationsulfate wastewater discharged into the environment can produce a series of pollution and ecological damages. We collected the water and sediment samples from a basin affected by acid mine drainage in a karst area of Zhijin County, Guizhou Province and investigated the migration and transformation of sulfate in the steam system. The results showed that water acidification in the study area occurred obviously. The dissolved form of sulfur in water was mainly SO42-, which had obvious attenuation in the process of water migration. Meta-stable sulfur content was low in sediments, while the exchangeable sulfate (ExS) was the dominant sulfur forms, accounting for 65% of the total sulfur (TS). The content of reduced sulfur was very low in the strong oxidizing environment. The content of different forms of reduced sulfur was in order of elemental sulfur (ES) < acid volatile sulfide (AVS) < chromium reduction sulfide (CRS). SO42- in water showed a positive relationship with Fe(Ⅲ). The co-precipitation of SO42- and Fe(Ⅲ) into the sediment is the main cause for the reduction of SO42-.

Key words: ecological sensitivity evaluation, urban development boundary, Nanchang City, CA-Markov