酸性硫酸盐土中铝的形态

应用生态学报 ›› 2000, Vol. ›› Issue (5): 735-740.

酸性硫酸盐土中铝的形态

王建武, 骆世明, 冯远娇

华南农业大学热带亚热带生态研究所, 广州510642

收稿日期:2000-05-23 修回日期:2000-07-05 出版日期:2000-09-25
通讯作者: 王建武,男,1966年生,博士,副教授,主要从事土地生态学和“3S”技术应用研究,发表论文30余篇,与人合作出版专(译)著2部.现主持国家“九*五”攻关子课题、国际合作、广东省科委、广东省自然科学基金等6项课题
基金资助:
澳大利亚ARC基金会资助;广东省自然科学基金资助项目(980161);广东省高等院校博士后科学研究基金资助

Aluminum forms in Acid Sulfate Soils

WANG Jianwu, LUO Shiming, FENG Yuanjiao

Institute of Tropical and Subtropical Ecology, Guangzhou 510642

Received:2000-05-23 Revised:2000-07-05 Online:2000-09-25

摘要/Abstract

摘要： 采用连续分级提取方法,把酸性硫酸盐土中可提取的非晶体态铝区分为交换态铝(ExAl)、吸附态无机羟基铝(HyAl)、有机配合铝(OrAl)、氧化铁结合铝(DCBAl)、层间铝(InAl)和非晶体态铝硅酸盐(NcAl),其平均值分别为1.79、2.51、4.17、4.14、4.31和18.66g·kg^-1Al₂O₃.实际酸性硫酸盐土中NcAl>OrAl>InAl>DCBAl>ExAl>HyAl,潜在酸性硫酸盐土NcAl>InAl>DCBAl>HyAl>OrAl>ExAl.可提取Al总量平均为35.57Al2O₃g·kg^-1,占全Al25.04%.其显著特征是活性铝ExAl、HyAl和OrAl的含量较高.每一种Al形态的结构组成与酸性硫酸盐土相应性质和生态特性密切相关.酸化的ASS的强酸环境导致Al的过量游离,并转化为活度较大的活性Al,从而产生Al毒.

Abstract: With the method of sequential extraction,the extractable noncrystalline aluminum in Acid Sulfate Soils was fractionized into exchangeable Al (ExAl),absorbed inorganic hydroxy-Al(HyAl),organic complexed Al(OrAl),Fe oxide bound Al (DCBAl),interlayered Al(InAl) and noncrystalline aluminosilicate(NcAl) with average of 1.79,2.51,4.17,4.14, 4.31 and 8.66gAl₂O₃.kg^-1,respectively.In actual Acid Sulfate Soils, the amount of different forms Al followed the order of NcAl>OrAl>InAl>DCBAl>ExAl>HyAl, but in potential acid sulfate soils, NcAl>InAl>DCBAl> HyAl>OrAl>ExAl. The average of the total extractable noncrystalline Al was 35.57 g Al₂O₃.kg^-1,which covered 25.04 % of the total amount of Al in Acid Sulfate Soils. The characteristic of extractable noncrystalline Al in Acid Sulfate Soils was the high proportion of active aluminum, such as ExAl,HyAl and OrAl. All forms of Al were closely related to the corresponding properties and ecological characteristics of Acid Sulfate Soils. The strong acid environment of actual Acid Sulfate Soils induced over released Al, which transformed to active Al and resulted in Al toxicity.

王建武, 骆世明, 冯远娇. 酸性硫酸盐土中铝的形态[J]. 应用生态学报, 2000, (5): 735-740.

WANG Jianwu, LUO Shiming, FENG Yuanjiao. Aluminum forms in Acid Sulfate Soils[J]. Chinese Journal of Applied Ecology, 2000, (5): 735-740.

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