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青藏高原小流域化学风化过程及其CO2消耗通量:以尼洋河为例

刘旭1,2,张东3,高爽1,2,吴婕1,2,郭建阳1,赵志琦1*   

  1. (1中国科学院地球化学研究所环境地球化学国家重点实验室, 贵阳 550081;2中国科学院大学, 北京 100049; 3河南理工大学资源环境学院, 河南焦作 454000)
  • 出版日期:2018-03-10 发布日期:2018-03-10

Chemical weathering and CO2 consumption flux in Tibetan Plateau: A case of NiyangRiver catchment.

LIU Xu1,2, ZHANG Dong3, GAO Shuang1,2, WU Jie1,2, GUO Jian-yang1, ZHAO Zhi-qi1*   

  1. (1State Key Laboratory of Environmental Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550081, China; 2University of Chinese Academy ofSciences, Beijing 100049, China; 3Institute of Resources and Environment, Henan PolytechnicUniversity, Jiaozuo 454000, Henan, China).
  • Online:2018-03-10 Published:2018-03-10

摘要: 青藏高原是研究构造隆升地表风化气候变化关系的理想场所。以尼洋河流域为研究对象,借助水化学和正演模型,研究硫酸参与的地表风化过程及其对区域CO2消耗通量和气候变化的影响。结果表明:(1)尼洋河河水的水化学类型主要为HCO3·SO4 Ca·Mg和HCO3·SO4Ca型,河水阳离子主要来源于碳酸盐和硅酸盐矿物化学风化,分别贡献了河水阳离子总量的79.4%和11.7%;(2)流域内发生了明显的硫化物矿物的化学风化现象,其风化速率(13.5 t·km-2·a-1)为流域内硅酸盐矿物风化速率(4.46 t·km-2·a-1)的3倍;(3)硫酸参与碳酸盐矿物化学风化引起的CO2净释放量在很大程度上抵消了流域内碳酸盐和硅酸盐矿物化学风化引起的CO2消耗通量。

关键词: 喀斯特坡地, 土壤机械组成, 降雨, 浅层裂隙, 地下土壤漏失

Abstract: Tibetan Plateau is an ideal place to study the relationship between tectonic uplift,surface weathering and climate change. Here, the role of sulfuric acid in carbonate and silicate weathering and its effects on the corresponding CO2 consumption flux and climate change were investigated in Niyang River catchment using hydrochemical method and forward model. The results showed that: (1) The hydrochemical type of Niyang River was characterized by HCO3·SO4Ca·Mg and HCO3·SO4Ca. The cations in river water were mainly derived from weathering of carbonate and silicate, contributing to 79.4% and 11.7% of the total water cation, respectively. (2) There was substantial chemical weathering of sulfide minerals in the catchment, with weathering rate (13.5 t·km-2·a-1) being three times as high as that of the silicate mineral weathering (4.46 t·km-2·a-1). (3) The net CO2 emissions during chemical weathering of carbonateresulted by sulfuric acid, to a large extent, could offset the CO2 consumption caused bycarbonate silicate mineral weathering in Niyang River catchment.

Key words: Karst slope, soil mechanical composition, leakage of underground soil, rainfall, shallow fissure