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生态学杂志 ›› 2011, Vol. 30 ›› Issue (07): 1467-1472.

• 研究报告 • 上一篇    下一篇

青海湖沉积物中多环芳烃的沉积记录

郭建阳1**,廖海清2,张亮2,汤智2,吴丰昌2   

  1. 1中国科学院地球化学研究所环境地球化学国家重点实验室, 贵阳 550002;2中国环境科学研究院湖泊生态环境研究中心国家环境保护湖泊污染国家重点实验室, 北京 100080
  • 出版日期:2011-07-08 发布日期:2011-07-08

Historical records of sediment polycyclic aromatic hydrocarbons in Qinghai Lake, Northwest China.

GUO Jian-yang1**, LIAO Hai-qing2, ZHANG Liang2, TANG Zhi2, WU Feng-chang2   

  1. 1State Key Laboratory of Environmental Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550002, China;2State Environmental Protection Key Laboratory for Lake Pollution Control, Research Center of Lake Eco-Environment, Chinese Research Academy of Environmental Sciences, Beijing 100080, China
  • Online:2011-07-08 Published:2011-07-08

摘要: 采用GC/MS方法分析了青海湖沉积柱中16种美国EPA优先控制的多环芳烃(TPAHs)的垂直分布状况,并对其来源进行了分析。研究表明,0~20 cm沉积柱中TPAHs的含量为495.1~1172.5 ng·g-1,随沉积年代的更新TPAHs的含量呈增加趋势。这与珠江口和东海沉积柱中的记录基本一致,但明显不同于发达国家同类研究的结果。青海湖沉积物PAHs以2~3环(包括萘、苊、苊烯、芴、菲和蒽)为主,其含量平均占沉积物中PAHs总量的(72.4±8.9)%。青海湖沉积物中的PAHs主要来自长距离的大气传输,家庭燃煤与木材的低温燃烧是其主要来源,高温燃烧过程释放的PAHs(如机动车尾气的排放)近年来有明显增加的趋势。

关键词: 蚯蚓, 甲胺磷, 乙草胺, Cu, 复合污染, 生态毒性

Abstract: By adopting GC/MS techniques, this paper analyzed the vertical distribution of 16 priority polycyclic aromatic hydrocarbons (PAHs) proposed by US EPA in a dated 0-20 cm sediment core from Qinghai Lake in Northwest China, and identified the possible sources of the PAHs. The total PAHs (sum of 16 the priority PAHs, TPAHs) concentration in the core ranged from 495.1 to 1172.5 ng·g-1, and had an increasing trend from deeper layer to surface layer. The vertical profile of the sediment PAHs in Qinghai Lake was basically similar to that in the East China Sea and the Pearl River Estuary, but clearly different from that in developed countries. The sediment PAHs in Qinghai Lake were dominated by 2-3 rings PAHs (including naphthalene, acenaphthylene, acenaphthene, fluorene, phenanthrene, and anthracene), accounting for 72.4%±8.9% of TPAHs on an average. The sediment PAHs in Qinghai Lake were mainly originated from the long-distance atmospheric transport resulting from low temperature combustion of domestic coal and woods, but the PAHs from high temperature process (such as vehicle emission) had an obvious increasing trend in recent years.

Key words: Earthworm, Methamidophos, Acetochlor, Cu, Combined pollution, Ecological toxicity