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生态学杂志 ›› 2010, Vol. 29 ›› Issue (12): 2486-2490.

• 研究报告 • 上一篇    下一篇

太子河水体中多环芳烃分布与污染源解析

宋雪英1**,李玉双1,伦小文2,蔺昕1,翟羽新1,胡晓钧1,孙铁珩1,3   

  1. 1区域污染环境生态修复教育部重点实验室|沈阳大学|沈阳 110044;2沈阳药科大学|沈阳 110016;3中国科学院沈阳应用生态研究所|沈阳 110016
  • 出版日期:2010-12-08 发布日期:2010-12-08

Distribution and related source identification of polycyclic aromatic hydrocarbons in surface water of Taizi River.

SONG Xue-ying1, LI Yu-shuang1, LUN Xiao-wen2, LIN Xin1, ZHAI Yu-xin1, HU Xiao-jun1, SUN Tie-heng1,3   

  1. 1Key Laboratory of Regional Environment and Eco-Remediation, Ministry of Education, Shenyang University, Shenyang 110044, China|2Shenyang Pharmaceutical University, Shenyang 110016, China|3Institute of Applied Ecology, Chinese Academy of Sciences, Shenyang 110016, China
  • Online:2010-12-08 Published:2010-12-08

摘要: 利用振荡提取-硅胶柱净化-HPLC荧光(FLD)/二级阵列检测器(DAD)检测法测定了太子河水中USEPA 16种优控多环芳烃(PAHs)的含量。结果表明,枯水期(4月)、丰水期(7月)和平水期(10月)太子河水中PAHs总浓度分别为454.5~1379.7、1801.6~5868.9和367.0~5794.5 ng·L-1,同国内外河流相比,太子河水中PAHs污染较严重,且具有明显的季节分布特征,丰水期PAHs浓度远高于枯水期。丰水期、平水期和枯水期太子河水中均以2~3环PAHs为主,但不同季节代表性PAHs的种类不同。污染来源分析表明,枯水期太子河水中PAHs主要来源于石油污染,丰水期和平水期主要来源于石油源和燃烧源的混合源。

关键词: 无公害农药, 农业措施, 水稻, 病虫草, 防效

Abstract: By the methods of shaking extraction-silica gel pole purification-high performance liquid chromatography detection with fluorescence detector and DAD detector, this paper measured the concentrations of 16 polycyclic aromatic hydrocarbons (PAHs) listed in the USEPA blacklist in the surface water of Taizi River. In dry season (April), wet season (July), and median water period (October), the total PAHs (TPAHs) concentration in the surface water was ranged in 454.5-1379.7 ng·L-1, 1801.6-5868.9 ng·L-1, and 367.0-5794.5 ng·L-1, respectively. The surface water of Taizi River was more seriously contaminated by PAHs, compared with that of other rivers in the world. The distribution characteristics of PAHs differed greatly with seasons. In each sampling station, the TPAHs concentration in wet season was much higher than that in dry season. The 2-ring and 3-ring PAHs were the most common components in Taizi River, either in dry season, wet season, or in median water period. The representative speciation of PAHs also differed with seasons. The source identification of PAHs inferred that petroleum was the main PAHs source in dry season, while the combination of petroleum discharge and fuel combustion contributed most to the PAHs in wet season and median water period.

Key words: Biorational pesticide, Agricultural methods, Rice, Pest organism, Efficacy