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镉同位素技术在环境科学研究中的应用进展

魏荣菲1,2,郭庆军1**,杨俊兴1,朱光旭1,2,张晗芝1,2,Marc PETERS1,王春雨1,2,万鹰昕3   

  1. (1中国科学院地理科学与资源研究所环境修复与资源工程研究室, 北京 100101; 2中国科学院大学, 北京 100049; 3北京联合大学应用文理学院, 北京 100191)
  • 出版日期:2014-02-10 发布日期:2014-02-10

Application and progress of Cd isotope technology in environmental science.

WEI Rong-fei1,2, GUO Qing-jun1**, YANG Jun-xing1, ZHU Guang-xu1,2, ZHANG Han-zhi1,2, Marc PETERS1, WANG Chun-yu1,2, WAN Ying-xin3   

  1. (1 Center for Environmental Remediation, Institute of Geographic Sciences and Natural Resources Research, Chinese Academy of Sciences, Beijing 100101, China; 2 University of Chinese Academy of Sciences, Beijing 100049, China; 3College of Arts and Science, Beijing Union University, Beijing 100191, China)
  • Online:2014-02-10 Published:2014-02-10

摘要: 近年来,镉(Cd)环境污染问题日趋严重,查明污染源并从源头上加以控制,对实施污染治理改变环境现状有十分重要的意义,而Cd同位素技术作为环境污染示踪剂已经在环境科学研究中发挥着重要作用。本文通过查阅近年来国内外对环境中Cd同位素技术的最新研究,探讨了Cd同位素的示踪原理、纯化分离、测定方法、仪器歧视校正方法、标准溶液的选取、Cd同位素组成及分馏机理以及Cd同位素在环境科学研究中的应用,并根据以往研究的不足和存在的问题,对今后研究工作的重点做出展望:Cd同位素的标准样品需要统一;根据不同样品中Cd的浓度选取不同的Cd同位素测定方法和校正方法;自然物质中Cd同位素组成数据仍需完善,Cd同位素分馏机理有待于进一步研究,Cd同位素应用前景有待于进一步开阔。

关键词: 景观空间格局, 动态转移, CLUE-S模型, 太湖流域, 景观指数

Abstract: Recently, the environmental pollution by the heavy metal cadmium has become more and more serious. In order to improve environmental quality, it is very significant to identify and control the sources of Cd pollution. Cd isotopes have played an important role as powerful tracers in environmental science. Referring to the latest research of Cd isotopes, this paper discusses Cd isotopic principles, separation of Cd from samples, selection of the standard solutions, the method of determination and instrument mass fractionation correction, Cd isotopic composition and fractionation mechanism, and the application of Cd isotopes in environmental science. Considering the methods and procedures applied for previous studies, certain modifications with respect to the application of Cd isotopes in environmental science should be carried out. The Cd isotopic standard solutions should be unified. The methods of determining the composition of Cd isotopes and correcting instrument mass fractionation should be selected according to the Cd concentrations in different samples. More information on Cd isotopic compositions of natural substances is needed and the fractionation mechanism of Cd isotopes has to be further studied.

Key words: landscape spatial pattern, dynamic transfer, landscape index, Taihu Lake basin., CLUE-S model