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土壤环境多氯二苯并二噁英/呋喃(PCDD/Fs)污染及其修复研究进展

张杏丽,周启星**   

  1. (南开大学环境科学与工程学院, 环境污染过程与基准教育部重点实验室/天津市城市生态环境修复与污染防治重点实验室, 天津 300071)
  • 出版日期:2013-04-10 发布日期:2013-04-10

Soil polychlorinated dibenzo-p-dioxins and dibenzofurans contamination and its remediation: Research progress. 

ZHANG Xing-li, ZHOU Qi-xing**   

  1. (Key Laboratory of Pollution Processes and Environmental Criteria (Ministry of Education)/Tianjin Key Laboratory of Environmental Remediation and Pollution Control, College of Environmental Science and Engineering, Nankai University, Tianjin 300071, China)
  • Online:2013-04-10 Published:2013-04-10

摘要: 多氯二苯并二噁英/呋喃(PCDD/Fs)是持久性有毒有机污染物,易沉积在土壤环境中,通过生物放大和生物富集最终输入到人和动物体内,对生态系统和人体健康有极大的威胁。本文在对PCDD/Fs环境行为与污染来源进行阐述的基础上,概述了PCDD/Fs污染的地域性特点以及土壤中PCDD/Fs的背景值和污染控制参考值;分析了我国土壤PCDD/Fs污染状况和潜在污染源,江西、广州贵屿、长江三角洲、台湾南部、浙江台州、天津某化工厂等6个区域污染较严重,主要污染源有含氯化学品的生产与使用,垃圾焚烧和纸浆生产。最后,介绍了PCDD/Fs污染土壤的处置方法与修复技术,主要有物理化学处置方法、微生物修复方法、植物修复方法、植物-微生物联合修复方法,并对今后该研究方向进行了展望。

关键词: 4-葡萄糖苷酶, 温度敏感性, 土壤有机碳矿化速率, 酶动力学, &beta, -1, 温带森林

Abstract: Polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs), as the persistent toxic organic pollutants, are easily to be deposited in soil environment, and finally enriched in human and animal bodies through biomagnification and bioaccumulation, bringing significant threat to ecosystems and human health. On the basis of expounding the environmental behaviors and pollution sources of PCDD/Fs, this paper summarized the regional characteristics of PCDD/Fs contamination and the background values and pollution control reference values of PCDD/Fs in soils, and analyzed the pollution status of PCDD/Fs in soils of China and the possible sources of PCDD/Fs. In China, six areas were seriously PCDD/Fs contaminated, i.e., Jiangxi, Guiyu of Guangzhou, the Yangtze River Delta, southern Taiwan, Taizhou of Zhejiang, and a chemical plant in Tianjin. The main pollution sources were the production and utilization of chlorinechemicals, waste incineration, and pulp production. The treatment approaches and remediation technologies for PCDD/Fs contaminated soils were recommended, including physicochemical approaches, microbial remediation, phytoremediation, and phytomicrobial remediation, and the future research directions were prospected.

Key words: soil organic carbon mineralization rate, enzyme kinetics, β-1,4-glucosidase, temperature sensitivity, temperate forest.