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福寿螺螺壳对水溶液中Pb2+的去除及其机理

赵本良1,2,3,彭卉1,章家恩1,2,3**,戴晓燕1,彭莉1   

  1. 1 华南农业大学热带亚热带生态研究所, 广州 510642; 2华南农业大学农业部生态农业重点开放实验室, 广州 510642; 3 广东省高等学校农业生态与农村环境重点实验室, 广州 510642)
  • 出版日期:2013-01-10 发布日期:2013-01-10

Lead removal from aqueous solution by the shell of golden apple snail and related mechanisms. 

ZHAO Ben-liang1,2,3, PENG Hui1, ZHANG Jia-en1,2,3**, DAI Xiao-yan1, PENG Li1   

  1. (1Institute of Tropical and Subtropical Ecology, South China Agricultural University, Guangzhou 510642, China; 2Key Laboratory of Ecological Agriculture of Ministry of Agriculture of the People’s Republic of China, Guangzhou 510642, China;3 Key Laboratory of Agroecology and Rural Environment of Guangdong Regular Higher Education Institutions, South China Agricultural University, Guangzhou 510642, China)
  • Online:2013-01-10 Published:2013-01-10

摘要: 福寿螺是世界100种恶性外来入侵物种之一。本研究探索了福寿螺螺壳作为吸附材料去除水溶液中Pb2+的特性和机理。结果表明,螺壳粉末对Pb2+的去除率与粉末用量、Pb2+初始浓度、溶液pH值和反应时间有关,水温对其去除率影响不大。Langumir模型拟合结果表明,螺壳粉末对Pb2+的吸附容量为89.29 mg·g-1。扫描电镜分析表明,螺壳粉末去除Pb2+的过程主要发生在其表面,小颗粒反应活跃。X射线衍射图谱表明,被吸附的Pb2+以PbCO3的形式存在于螺壳粉末中,去除Pb2+的机理可能是消耗螺壳中方解石和文石时的离子交换和沉淀反应。研究表明,福寿螺螺壳可成为一种有效的重金属Pb2+吸附剂。

Abstract: Golden apple snail is one of the 100 pernicious alien invasive species in the world.  In this study, the shell powder of golden apple snail was used as the adsorbent to approach its characteristics and mechanisms of lead (Pb2+) removal from aqueous solution under laboratory condition. It was found that the removal rate of Pb2+ by the shell powder was related to the shell powder amount, initial Pb2+ concentration, solution pH, and reaction time, while solution temperature had lesser effects. The fitting of Langumir model indicated that the Pb2+ adsorption capacity of the shell powder was 89.29 mg·g-1. The analysis of scanning electron microscopy showed that the Pb2+ removal process was mainly happened at the surface of the powder, and small particle was more active. The X-ray diffraction indicated that the adsorbed Pb2+ was in the form of PbCO3 existing on the powder. The mechanisms of the Pb2+ removal could be the ion exchange and precipitation on the aragonite and calcite in the powder. It was suggested that the shell of golden apple snail could be used as an effective bio- adsorbent for Pb2+ removal.